ASTPEEN Polymer Permanent Antistatic Agent Series (Antistatic Agent, Antistatic Masterbatch, Antistatic Material)

ASTPEEN Polymer Permanent Antistatic Agent Series (Antistatic Agent, Antistatic Masterbatch, Antistatic Material)

Functional polymer materials

The ASTPEEN series of polymer permanent antistatic agents is a professional synthetic and produced polymer polyether ester amide permanent antistatic agent by our company. This product mainly forms a unique micro conductive network structure in the polymer matrix to leak charges and achieve efficient and long-lasting anti-static function. Unlike traditional anti-static agents, the anti-static performance of this product does not rely on migration to the surface of the product, nor does it depend almost on external temperature and humidity. Therefore, it has outstanding advantages such as long-lasting effect, no influence from wiping or washing, no impact on product transparency and mechanical properties. After adding ASTPEEN polymer permanent antistatic agent, the surface resistance can reach 10E6-12Ω Special anti-static performance requirements can be made into 10E5Ω Below, a conductive polymer is formed.

(1)Product FeaturesThe following are:

1、 Forever efficient: The anti-static performance will not deteriorate over time, surface wiping, or solvent cleaning, and will remain effective throughout the product's lifespan.

2、 Toughening modification: It can be used alone as an elastomer to improve the impact resistance (toughness) of the matrix material.

3、 Stable performance: Meets strict processing temperatures and methods, almost unaffected by external environmental factors such as temperature/humidity and wear.

4、 The impact on mechanical properties is minimal: it has little effect on the mechanical strength, heat resistance, and processing flowability of the matrix material.

5、 Good compatibility: It has good compatibility, and different types of anti-static agents correspond to almost all polymer materials, which are not easy to precipitate and do not affect subsequent printing, spraying or bonding processes.

6、 Convenient color matching: It can fully meet the needs of color matching.

7、 Excellent Transparency: The addition of corresponding anti-static agents has minimal impact on the transparency of the matrix resin, making it particularly suitable for applications that require high transparency.

(II) ASTPEEN series polymer permanent antistatic agent models and their application scope

Model

Appearance

Surface resistance

Hardness

Melting point

Recommended materials and processes

ASTPEEN100

 

≤ E6Ω

80A

130/150℃

1. Directly used in soft transparent materials such as TPU, PVC, TPE, POE, EVA, extrusion, injection molding, blow molding, and foaming

2. Used for extrusion (sheet), injection molding and blow molding (film) and foaming of PP, LLDPE, LDPE, HDPE

ASTPEEN200

 

≤ E6Ω

45D

85℃

Recommended for extrusion and injection molding of PBT, TPEE, TPU, ABS, etc

ASTPEEN300

 

≤ E6Ω

95A

190℃

Recommended for blown film of PA and its elastomers PP, PE, and transparent materials of ABS, PMMA

ASTPEEN301

 

≤ E7Ω

63D

215℃

Recommended for injection molding, blown film of PA, ABS, PP, HDPE, PC, PET, PPO \ PPS \ PEEK, high-temperature nylon, etc

ASTPEEN310

 

≤ E6Ω

95A

180℃

Recommended for injection molding of thermally unstable products such as POM, as well as PA, ABS, ASA

ASTPEEN600

 

≤ E6Ω

95A

200℃

Recommended for injection molding and extrusion of sheets such as HIPS, ABS, TPEE, PC, PP, etc

ASTPEEN800

 

≤ E6Ω

70A

150/170℃

Recommended for use in transparent materials such as TPU, PVC, TPE, ABS, POE, SBS, ASA, PP, etc

ASTPEEN806

 

≤ E6Ω

50D

200℃

Recommended for use in materials with high processing temperatures and surface hardness requirements such as PC, ABS, PBT, PET, TPEE, etc., for extrusion (board, sheet), injection molding, molding and other processes

ASTPEEN8800 series

 

≤ E9Ω

95A

180℃

Recommended for transparent materials such as GPPS (8801), ABS (8802), PMMA (8805), PC/PET (8808), PP/PE (8818), etc

 

ASTPEEN900 series

 

E6-11Ω

Soluble in water and other polar solvents

-35℃

1. Recommended for coating, pouring, molding processes such as latex, liquid silicone, liquid polyurethane, epoxy resin, paint, etc

2. Waterproof, alcohol and solvent scrubbing, strong adhesion, used for various surface coatings

 

(Three)Typical substrates that can be selectedASTPEEN series polymer permanent antistatic agentsModels and precautions

Raw materials

Anti static agent model

(sorted by priority)

Add quantity

(E6-9Ω)

Precautions

Remarks

PS

600#、316#A

15-30%

Need to extract particles (add about 3% compatibilizer), can extrude sheet material

316 # A is suitable for halogen-free

ABS

200#、300#、600#

15-30%

Mixable injection molding, squeezable sheet material

300 # is suitable for transparency

TPE

100#、600#

15-30%

100 # is suitable for low hardness, 600 # is suitable for high hardness, mixable injection molding

100 # can be made transparent

TPU

100#、600#

15-30%

100 # Transparent and mixable injection molding

600 # Suitable for natural color

TPEE

100#、200#、600#

15-30%

100 # for low hardness

600 # Suitable for extrusion grade

Rubber

100DRD

15-30%

Mixing dispersion

 

EVA

100

15-30%

Blended injection molding

 

  PC、PC/ABS

301、

806#、8808#

15-30%

Add anti hydrolysis agent, ester exchange inhibitor, and dry to control moisture content within 0.05%

8808 # Suitable for Transparency

PET

600#、806#、8806#

15-30%

Add anti hydrolysis agent, ester exchange inhibitor, and dry to control moisture content within 0.05%

8806 # Suitable for Transparency

PA

300、301、308

15-30%

Blended injection molding, can draw threads

301 # is suitable for extrusion grade, wire drawing

PBT

200#、600#

15-30%

Blended injection molding, can draw threads

600 # Suitable for extrusion grade

PP

100#、600#、813

15-30%

Need to extract pellets (add about 3% compatibilizer) for extruded sheets, injection molded plates, frames, etc

600 # Suitable for extrusion grade

LLDPE

100#

15-30%

blown film

 

LDPE、HDPE

100#、300、301、600#

15-30%

Need to extract particles (add about 3% compatibilizer)

600 # Suitable for extrusion grade

PPO、PEEK、LCP

301#、310#

15-30%

Need to extract particles

Pay attention to controlling the processing temperature

POM

310#

15-30%

Granulation

Can be board, rod, injection molded

PMMA

300#、8805#

15-30%

Granulation, mixable injection molding

Transparent

 

(Four)ASTPEEN series polymer permanent antistatic agentPerformance summary

Test project

Testing method

Type 100

Type 200

Type 300

Type 301

Type 310

Type 600

Type 800

Type 806

Tensile strength, 25 ℃, MPa

GB/T  528

7.3

10.8

8.0

61.8

6.8

12.2

7.3

8.0

Elongation at break, 25 ℃,%

GB/T 528

734

261

1079

768

100

788

1322

415

Shore hardness, 3s, HD

GB/T 2411

25

44.5

25

62.5

35

46.5

25

31

Density, g/cm3

GB/T 533

1.226

1.260

1.065

1.163

1.188

1.222

1.241

1.207

Surface resistance value,Ω

GB/T  1410

5.8*105

5.7*106

1.1*107

2.4*107

1.7*106

1.6*106

1.5*106

1.2*106

Melt flow rate, g/10min

(190℃,2.16kg)

GB- 3682

42.9

-

26.4

-

6.45

-

-

-

Melt flow rate, g/10min (200 ℃, 2.16kg)

GB- 3682

-

-

-

-

-

-

27

-

Melt flow rate, g/10min (210 ℃, 2.16kg)

GB- 3682

-

33.96

-

-

-

10.62

-

-

Melt flow rate, g/10min (220 ℃, 2.16kg)

GB- 3682

-

-

-

15.4

-

-

-

0.24

Melt flow rate, g/10min (220 ℃, 5kg)

GB- 3682

-

-

-

-

-

-

-

1.78

(Five)ASTPEEN series polymer permanent antistatic agentsApplication fields

ASTPEEN polymer permanent antistatic agent is mainly used in the following fields:

Plastic processing:

        

          Blow molded film;                     Injection molded profiles

 

Industrial tools:

     

                Conveyor belt;                             Tool cart

 

Electronics industry:

       

        Electronic component tray;                               Fixture

 

Cleanroom equipment:

     

              Workbench                    Anti static work clothes

(Six)ASTPEEN series polymer permanent antistatic agentTypical application examples

PS, ABS, and PP three-layer co extruded anti-static vacuum forming sheet materials are materials that simultaneously extrude three layers of films/sheets of different materials or functions and bond them together. They are usually designed with A-B-C or A-B-A structures, which combine the excellent properties of different materials together and solve the contradiction that a single material cannot simultaneously consider multiple properties.

The production of three-layer co extruded anti-static vacuum formed sheets is a systematic engineering that precisely combines material formulation (selection and addition of anti-static agents), equipment (co extrusion die design), and process (temperature, speed, etc.).

PS/ABS/PP Production process of vacuum formed sheet materials

 

Unit

PS

ABS

PP

Barrel temperature

Feeding section

150-170

170-190

180-210

Compression segment

160-180

180-200

190-230

Measurement section

170-190

190-210

200-230

Melting value

200

210

220

Screw speed

RPM

80-450

Operating current

A

100-240A

Operating pressure

Mpa

3-25

Feeding speed

RPM

2-40

 

The above table is a reference for single material extrusion. Three layer co extrusion requires setting separate temperatures for each independent extruder layer. The setting of barrel temperature does not have a fixed optimal solution, it is a dynamic adjustment process based on theory, combined with equipment, materials, and actual phenomena.

It is recommended to set the initial temperature based on the recommended values of the specific grade of resin and anti-static masterbatch you are using. After co extrusion, carefully observe the appearance and layering of the sheet, and adjust the temperature of each extruder (especially the metering section) and die slightly until a smooth surface, uniform thickness, and well bonded interlayer sheet is obtained.

 

Application example:

On site pictures:

 

Detailed Introduction

The ASTPEEN series of polymer permanent antistatic agents is a professional synthetic and produced polymer polyether ester amide permanent antistatic agent by our company. This product mainly forms a unique micro conductive network structure in the polymer matrix to leak charges and achieve efficient and long-lasting anti-static function. Unlike traditional anti-static agents, the anti-static performance of this product does not rely on migration to the surface of the product, nor does it depend almost on external temperature and humidity. Therefore, it has outstanding advantages such as long-lasting effect, no influence from wiping or washing, no impact on product transparency and mechanical properties. After adding ASTPEEN polymer permanent antistatic agent, the surface resistance can reach 10E6-12Ω Special anti-static performance requirements can be made into 10E5Ω Below, a conductive polymer is formed.

(1)Product FeaturesThe following are:

1、 Forever efficient: The anti-static performance will not deteriorate over time, surface wiping, or solvent cleaning, and will remain effective throughout the product's lifespan.

2、 Toughening modification: It can be used alone as an elastomer to improve the impact resistance (toughness) of the matrix material.

3、 Stable performance: Meets strict processing temperatures and methods, almost unaffected by external environmental factors such as temperature/humidity and wear.

4、 The impact on mechanical properties is minimal: it has little effect on the mechanical strength, heat resistance, and processing flowability of the matrix material.

5、 Good compatibility: It has good compatibility, and different types of anti-static agents correspond to almost all polymer materials, which are not easy to precipitate and do not affect subsequent printing, spraying or bonding processes.

6、 Convenient color matching: It can fully meet the needs of color matching.

7、 Excellent Transparency: The addition of corresponding anti-static agents has minimal impact on the transparency of the matrix resin, making it particularly suitable for applications that require high transparency.

(II) ASTPEEN series polymer permanent antistatic agent models and their application scope

Model

Appearance

Surface resistance

Hardness

Melting point

Recommended materials and processes

ASTPEEN100

 

≤ E6Ω

80A

130/150℃

1. Directly used in soft transparent materials such as TPU, PVC, TPE, POE, EVA, extrusion, injection molding, blow molding, and foaming

2. Used for extrusion (sheet), injection molding and blow molding (film) and foaming of PP, LLDPE, LDPE, HDPE

ASTPEEN200

 

≤ E6Ω

45D

85℃

Recommended for extrusion and injection molding of PBT, TPEE, TPU, ABS, etc

ASTPEEN300

 

≤ E6Ω

95A

190℃

Recommended for blown film of PA and its elastomers PP, PE, and transparent materials of ABS, PMMA

ASTPEEN301

 

≤ E7Ω

63D

215℃

Recommended for injection molding, blown film of PA, ABS, PP, HDPE, PC, PET, PPO \ PPS \ PEEK, high-temperature nylon, etc

ASTPEEN310

 

≤ E6Ω

95A

180℃

Recommended for injection molding of thermally unstable products such as POM, as well as PA, ABS, ASA

ASTPEEN600

 

≤ E6Ω

95A

200℃

Recommended for injection molding and extrusion of sheets such as HIPS, ABS, TPEE, PC, PP, etc

ASTPEEN800

 

≤ E6Ω

70A

150/170℃

Recommended for use in transparent materials such as TPU, PVC, TPE, ABS, POE, SBS, ASA, PP, etc

ASTPEEN806

 

≤ E6Ω

50D

200℃

Recommended for use in materials with high processing temperatures and surface hardness requirements such as PC, ABS, PBT, PET, TPEE, etc., for extrusion (board, sheet), injection molding, molding and other processes

ASTPEEN8800 series

 

≤ E9Ω

95A

180℃

Recommended for transparent materials such as GPPS (8801), ABS (8802), PMMA (8805), PC/PET (8808), PP/PE (8818), etc

 

ASTPEEN900 series

 

E6-11Ω

Soluble in water and other polar solvents

-35℃

1. Recommended for coating, pouring, molding processes such as latex, liquid silicone, liquid polyurethane, epoxy resin, paint, etc

2. Waterproof, alcohol and solvent scrubbing, strong adhesion, used for various surface coatings

 

(Three)Typical substrates that can be selectedASTPEEN series polymer permanent antistatic agentsModels and precautions

Raw materials

Anti static agent model

(sorted by priority)

Add quantity

(E6-9Ω)

Precautions

Remarks

PS

600#、316#A

15-30%

Need to extract particles (add about 3% compatibilizer), can extrude sheet material

316 # A is suitable for halogen-free

ABS

200#、300#、600#

15-30%

Mixable injection molding, squeezable sheet material

300 # is suitable for transparency

TPE

100#、600#

15-30%

100 # is suitable for low hardness, 600 # is suitable for high hardness, mixable injection molding

100 # can be made transparent

TPU

100#、600#

15-30%

100 # Transparent and mixable injection molding

600 # Suitable for natural color

TPEE

100#、200#、600#

15-30%

100 # for low hardness

600 # Suitable for extrusion grade

Rubber

100DRD

15-30%

Mixing dispersion

 

EVA

100

15-30%

Blended injection molding

 

  PC、PC/ABS

301、

806#、8808#

15-30%

Add anti hydrolysis agent, ester exchange inhibitor, and dry to control moisture content within 0.05%

8808 # Suitable for Transparency

PET

600#、806#、8806#

15-30%

Add anti hydrolysis agent, ester exchange inhibitor, and dry to control moisture content within 0.05%

8806 # Suitable for Transparency

PA

300、301、308

15-30%

Blended injection molding, can draw threads

301 # is suitable for extrusion grade, wire drawing

PBT

200#、600#

15-30%

Blended injection molding, can draw threads

600 # Suitable for extrusion grade

PP

100#、600#、813

15-30%

Need to extract pellets (add about 3% compatibilizer) for extruded sheets, injection molded plates, frames, etc

600 # Suitable for extrusion grade

LLDPE

100#

15-30%

blown film

 

LDPE、HDPE

100#、300、301、600#

15-30%

Need to extract particles (add about 3% compatibilizer)

600 # Suitable for extrusion grade

PPO、PEEK、LCP

301#、310#

15-30%

Need to extract particles

Pay attention to controlling the processing temperature

POM

310#

15-30%

Granulation

Can be board, rod, injection molded

PMMA

300#、8805#

15-30%

Granulation, mixable injection molding

Transparent

 

(Four)ASTPEEN series polymer permanent antistatic agentPerformance summary

Test project

Testing method

Type 100

Type 200

Type 300

Type 301

Type 310

Type 600

Type 800

Type 806

Tensile strength, 25 ℃, MPa

GB/T  528

7.3

10.8

8.0

61.8

6.8

12.2

7.3

8.0

Elongation at break, 25 ℃,%

GB/T 528

734

261

1079

768

100

788

1322

415

Shore hardness, 3s, HD

GB/T 2411

25

44.5

25

62.5

35

46.5

25

31

Density, g/cm3

GB/T 533

1.226

1.260

1.065

1.163

1.188

1.222

1.241

1.207

Surface resistance value,Ω

GB/T  1410

5.8*105

5.7*106

1.1*107

2.4*107

1.7*106

1.6*106

1.5*106

1.2*106

Melt flow rate, g/10min

(190℃,2.16kg)

GB- 3682

42.9

-

26.4

-

6.45

-

-

-

Melt flow rate, g/10min (200 ℃, 2.16kg)

GB- 3682

-

-

-

-

-

-

27

-

Melt flow rate, g/10min (210 ℃, 2.16kg)

GB- 3682

-

33.96

-

-

-

10.62

-

-

Melt flow rate, g/10min (220 ℃, 2.16kg)

GB- 3682

-

-

-

15.4

-

-

-

0.24

Melt flow rate, g/10min (220 ℃, 5kg)

GB- 3682

-

-

-

-

-

-

-

1.78

(Five)ASTPEEN series polymer permanent antistatic agentsApplication fields

ASTPEEN polymer permanent antistatic agent is mainly used in the following fields:

Plastic processing:

        

          Blow molded film;                     Injection molded profiles

 

Industrial tools:

     

                Conveyor belt;                             Tool cart

 

Electronics industry:

       

        Electronic component tray;                               Fixture

 

Cleanroom equipment:

     

              Workbench                    Anti static work clothes

(Six)ASTPEEN series polymer permanent antistatic agentTypical application examples

PS, ABS, and PP three-layer co extruded anti-static vacuum forming sheet materials are materials that simultaneously extrude three layers of films/sheets of different materials or functions and bond them together. They are usually designed with A-B-C or A-B-A structures, which combine the excellent properties of different materials together and solve the contradiction that a single material cannot simultaneously consider multiple properties.

The production of three-layer co extruded anti-static vacuum formed sheets is a systematic engineering that precisely combines material formulation (selection and addition of anti-static agents), equipment (co extrusion die design), and process (temperature, speed, etc.).

PS/ABS/PP Production process of vacuum formed sheet materials

 

Unit

PS

ABS

PP

Barrel temperature

Feeding section

150-170

170-190

180-210

Compression segment

160-180

180-200

190-230

Measurement section

170-190

190-210

200-230

Melting value

200

210

220

Screw speed

RPM

80-450

Operating current

A

100-240A

Operating pressure

Mpa

3-25

Feeding speed

RPM

2-40

 

The above table is a reference for single material extrusion. Three layer co extrusion requires setting separate temperatures for each independent extruder layer. The setting of barrel temperature does not have a fixed optimal solution, it is a dynamic adjustment process based on theory, combined with equipment, materials, and actual phenomena.

It is recommended to set the initial temperature based on the recommended values of the specific grade of resin and anti-static masterbatch you are using. After co extrusion, carefully observe the appearance and layering of the sheet, and adjust the temperature of each extruder (especially the metering section) and die slightly until a smooth surface, uniform thickness, and well bonded interlayer sheet is obtained.

 

Application example:

On site pictures: